Lesson 4 – Chemistry
Physical Chemistry:
- Structure of Atoms: the Nucleolus are- (Protons + Neutrons).
- An alpha particle contain (α- particle)- 2 positive charge and 4- mass Unit.
- Who discovered electrons- J.J Thomson?
- Formula for a mass number of an atom- ( No. of protons + No. of neutron)
- No. of electrons – determines of the chemical properties.
- Atoms that have the same mass number and different atomic number are called- Isotopes.
- The maximum mass of an atoms is concentrated in – Nucleus.
- If an atom’s atomic Number is given No. by N formula:
(N= A-Z) - α- particle is also known as- A helium Nucleus.\
- β- particle is also Known as- An electron
- Atomic theory of matter was given by Dalton.
- Ruther ford’s atomic model the electron inside an atom are- Non -stationary
- ∞- ray photons have- No mass and No. electric charge of +2.
- A device used for the measurement of Radioactivity is G.M Counter (Geiger-Muller counter)
- Hydrogen bomb is based on the principle of – Nuclear fusion.
- Phenomena of radioactivity was discovered by Herri Bequerel in 1896.
- α- particle kinetic energy (Maximum) α>β>∞ (minimum)
- α- particle ionizing radiation is (Alpha)
- Nuclear fusion element -Uranium (92U235)
- Radioactivity that takes the from high energy electromagnetic wave would be gamma.
- Which great scientist was discovered by alpha and beta (β) rays- Rutherford?
- The maximum number of electron presents in a subshell with formula – 2( 2l+1) (l= subshell)
Chemical Bonding
- The least electronegative element with (low ionization energy and low electron affinity (EA)
- Compared to compounds ionic generally have (High melting point and high boiling point)
- With increase in bond order, bond enthalpy increase and bond order length (Decreases)
- F2 and o2-2 have bond order -1, N2 ,co and NO+ have bond order 3
- Ethylene – gas used for artificial fruit ripening of green fruit.
- Highest lattice energy (increase), size of compound (decrease).
- Xef4 -square planer.
- Sp3 – Hybridisation in C2H6 (alkane)
- Sp2 – Hybridisation in C2H4 (alkene)
- Sp- Hybridisation in C2H4 (alkynes)
- Poor conductors of electricity is a characterise of – covalent compounds
- The maximum number of hydrogen bonds that a molecule of water can have is – 4
- The bond formation as a result of the electrostatic attraction between the positive and negative ions is termed as electrovalent Bond -Ionic bond.
- The lowest energy structure is the one with the formal charge on the atoms- smallest.
- The effect of more electronegative atom on the strength of ionic bond -increase.
- Zero dipole moment -BF3, Co2, CH4.(µ=0)
- Non-Zero dipole Moment- NF3, CH3Cl, ClO2, (µ≠0)
- H-Cl molecule contain – polar covalent Bond.
- ClO3– = Pyramidal geometry (VSEPR)
- Resonance is due to – Delocalization of Pi electrons.
- H2O -Molecule of high dipole moment is (Increase Electronegative, µ Increase )
- According to Fajan’s rule, Covalent Bond is favoured by -cation size (Decrease), anion size (Increase)
- CH4 – Shape- tetrahedral
- So3— -Shape- tetrahedral (Sp3)
- The high value of electron affinity -Cl
- O2 each Oxygen atom is hybridized – Sp2.
- Measurement of the degree of polarity is Dipole Moment.
- Geometry of Molecule will be pyramidal,
- If the outer post shell of the central atom has- 3 Bond pair one lone pair.
- Unpaired electron in a molecule gives paramagnetic character.
- Periodic Table-
- Left to right (increasing factor) – Ionization Energy, Electron affinity, Electronegativity.
- Isobars are line joining -equal pressure.
- Lubricant in heavy Machines used- Graphite.
- Potassium iodate- used to iodise common salt (KIO4).
- Up to down – Increasing – Atomic radius, Metallic Character,
- Decrease Factor- Non-metallic Character
- Down to up- Increasing- electron affinity ionization energy.
- Right to left- Increasing- Atomic radius.
- The arrangement of elements in the modern periodic table is based on their:
(increasing atomic No. in the Horizontal row)
- The electro positive character of elements on moving from left to right in a periodic table –Decrease.
- Transition metal of group elements -3 to 12 group No.
- “Baking Soda” -Sodium Bicarbonate (NaHCo3).
- “Sodium Carbonate”- Na2Co3 .10H2O (Washing Soda).
- Fermentation of Milk to Curd is due to –lactobacillus.
- Ozone depleting pesticide: Methyl Bromide.
- Metal and Non-Metal:
Metal | Non-Metal |
Metal and 1 to 3 electron in their outermost shell. | Non- Metal and 4 & 8 electron in their outermost shell. |
Metal are solid at room temperature | Non- metal are present in three states solid, Liquids and gases. |
Metal are generally Hard | Non- Metal are Soft. |
- Soft metal we can cut knife – Na, K, L
- Metal which is found in liquid state at room temperature is mercury.
- Aqua- ragia is a Mixture of Concentrated -(Hydrochloric + Nitric acid)
- Amphoteric oxide- is Zinc Oxide.
- Aluminium oxide also – amphoteric Behaviour.
- Metal do not form Hydrogen gas reacting with Nitric acid.
- The element other than mercury which is found is liquid state – Bromine.
- Alkali Metal has Highest Specific Heat- Lithium (Li) (Used as coolant)
- Natural Dye- Alizarin.
- Quartz is made of – Calcium Silicate.
- The ability of metals to be drawn into thin wire is called- ductility.
- Most Ductility Metal- gold
- Most Non- Metals produce oxides when dissolve in water- is acidic Nature but metal always show- Basic Nature.
- In Stainless steel alloy iron metal is mixed with – Cr and Ni (Cr is maximum quantity available.
- Sodium is kept in which of the following substance for storage- kerosene
- Calcium, Magnesium and Iron – the metallic constituent of hard water.
- The acid used in load storage cell is – H2So4.
- “Milk of Magnesia”- Mg (OH)2 (solid from name- Brucite).
- Soap is prepared by – Caustic soda(NaoH) + Animals fats
- Bronze is alloys – Copper + Tine(Cu + Sn)
- Brass is alloys- Copper + Zine (Cu + Zn)
- Amphoteric Oxide- React with (Acid + Base )Ex. Al2O3
- Anthracite -coal contain 90 % of carbon.
Organic Chemistry
Basic of Alkanes, Alkenes, Alkynes.
- Alkanes- CnH2n+2
- Alkenes- CnH2n
- Alkynes- CnH2n-2 (Bond Angle-180o)
- L.P.G is a Hydrocarbon consisting of a Mixture of (propane + Butane)
- Propane -Maximum Quantity available.
- Which among the following minerals is also known as Horn Silver- Silver chloride (AgCl2). (used in photochromic glass)
- Sodium Benzoate are used for preservation in Tomato Juice
- Quick Silver- Mercury (ore- Sinnebar)
- Cao -Quick Lime Slacket lime- Ca(OH)2
- Carbon Black is obtained from -Methane (CH4)
- Wood sprit – (CH3OH) Methanol.
- Crude Oil Separated- Fractional Distillation.
- Black Gold-petroleum.
- Gasohol- is mixture of = gasoline + Ethanol.
- Alkynes is used as a rocket fuel- propyne
- Hydrolysis (Saponification) of a fat would yield (Glycerol and Soap)
- What is old name of Alkene- Olefins?
- Ethyl Acetate- is used for Making perfume and Dyes
- In water alkanes are- insoluble water
- General formula of alcohol and phenol- CnH2n+2O
- A saturated Hydrocarbon is also an -alkane.
- Hydrocarbon with double or triple bonds are said to be -Unsaturated.
- Alcohol are soluble in Lucas reagent (Con. HCl + ZnCl2)
- Methanol – also Known as “Wood Sprit” was produced by destruction distillation of wood methanol- colourless, Poisons,
- Fermentation takes places in anaerobic condition i.e. in absence of air,Co2 is released during fermentation.
- Propanol -alcohol would be most soluble in water.
- Gases used for ripening raw fruits- & Acetylene
- Water soluble vitamin – B & C Ethylene
- Fat soluble vitamins – A,D,E,K
- What Blackens Silver’s Shine- Ozone Gas
- Cobalt is found in- Vitamin B12
- Sunlight & Fish Liner- Best Sources for Vitamin-D.
- Gases used by sea divers for breathing are – Oxygen & Helium.
- Zinc Phosphide is used as of – lead and Tin
- Purest form of Iron is- wrought iron (Carbon Contain-0.12 to 0.25%)
- Which agent is as seed in artificial rain (Silver Iodide) (AgI)
- Oxides of metal are- Alkaline during the process of “Rusting” the weight of iron -Increases.
- CaH2 (Calcium Hydride) is used to prepare fire prof and water proof Clothes.
- Chemical name of chromic Acid is- chromium trioxide (H2Cro4)
- Barium Hydroxide is also Known as Baryta water.
- Ammonia (NH3) is synthesized through Haber’s process.
- Chlorine is used to prepare- PVC, Insecticide, Herbicides.
- Platinum is also called “White Gold”
- N2O is known as laughing gas.
- Chloroform is sunlight form poisonous gas.
- Nail Polish remover contain- Acetone.
- Lightest metal: Lithium.
- Acid rain is due to air pollution by (Nitrous Oxides + Sulphur Dioxide)
- The lustre of metal is due to (presence of free electrons).
- Aspirin is Acetyl Salicylic Acid.
- Xeon- is also known as Stranger Gas.
- Oil of Vitriol is sulphuric acid (H2So4)
- Which is Known as “Metal of Future”- (Titanium)
- Kerosene is a Mixture of (Aliphatic Hydrocarbon).
- The important metal used with iron Produce stainless steel is chromium.
- Oxidation- Loss of electrons.
- The metal Constituent of Chlorophyll is Magnesium.
- Which Acid is used for etching gas – Hydrofluoric acid (HF)
- Paraffin Wax is – Saturated Hydrocarbon
- Golden Rice is rich in- Vitamin A.
- Philosopher’s wool is- Zno.
- CaSo4.2 H2O- gypsum.
- CaSo4.1/2 H2O- Plaster of Paris
- Bio- Fertilizer for Rice is – Azolla
- The gas used for artificial fruit ripening of green fruit is Ethylene( C2H4)
- “Bhopal gas tragedy” of 1984 is related to- Methyl isocyanate (CH3NCO)
- Hydrochloric Acid- Muriatic Acid.
- Greenhouse gases – CO2, CH4, N2O, CFC.
- Aerosol is example (fog, dust) – (Suspended solid particles is air)
- Electric Fuse is an alloy of – Tin and lead.
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- Tetraethyl lead(TEL) is (An antiknock compounds)
- Alcohol prepared by the distillation of wood is (Methyl Alcohol)
- One of the constituents of tear gas is Chloropicrin.
- Substance used as an antifreeze in Radiators or Automobiles is(CH3OH + H2O)
- Mercury- Metals from an Amalgam with other metals (X+ Metal -amalgam.
- Natural Dye- example of – Alizarin
- Milk of Magnesia is a suspension of – Magnesium Hydroxide
- German silver is an alloy of – Zn, Cu, Ni,
- HF- acid is used for the etching glass
- The flavour of apple is mainly due to- Ethanol
- Fool’s Gold (Pyride)- FeS2 (Iron Sulphide)
- Smoke is formed due to- Solid dispersed in gas
- Dissolved noble metals Aqua ragia (HNO3 + HCl) (Ratio 1:3) -(Au,Ag,Pt)
- Meneral containing both magnesium and calsium is- Dolomite (Ca Mg (Co3)2)
- Hydrogen bomb is based on the principle- Uncontrolled fusion reaction.
- A powerful eye intent present in song is – proxy acetyl nitrate
- Ozone layer is present in -Stratosphere.
- Stainless steel is usually made by alloying the steel with- chromium + Nickel
- The gaseous Mixture of (Co +N2) – producer gas
- Phenol is used as- Antiseptics.
- Old Name of Alkenes- Olefin
- The gas emancipating through paddy field is – Methane
- PAN- Peroxy acetyl Nitrate is a – Secondary Pollutant.
- Name a gas used as rocket propellant and in welding also- Cyanogen (CN)2
- In Picking and etching sulphuric acid are used.
- Phenol is used as- Antiseptic
- The graphite is – Diamagnetic
- Gun Powder- Potassium + Sulphur + Char Coal
- The green colour seen in firework display is due to the chloride salt of- Barium.
- Cholesterol is a fatty alcohol found in animal fat.
- PMN- Polymetallic Modules predominantly contain – Manganese.